1,3-Diphenylisobenzofuran
نویسندگان
چکیده
The structure of the title compound, 1,3-diphenyl-2-benzofuran, C(20)H(14)O, exhibits a distinct alternation of short [mean 1.361 (3) Å] and long [mean 1.431 (3) Å] C-C bonds around the benzofuran ring system, indicating a predominantly polyene character. Over 60 Diels-Alder adducts of this commercially available furan have been structurally characterized, but this is the first report of the structure of the parent compound.
منابع مشابه
Photobleaching of 1,3-diphenylisobenzofuran by novel phthalocyanine dye derivatives.
As part of a wider programme to identify novel photosensitizers for photodynamic therapy, the ability of a number of phthalocyanine dyes, including some novel copper phthalocyanine derivatives with a range of water solubilities, to produce potentially cytotoxic species in solution was examined. The experiments were performed in dimethylformamide using 1,3-diphenylisobenzofuran (DPIBF) as the sc...
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Singlet Oxygen, Radicals, Fluorescein, Diphenylisobenzofuran, Reversed Micelles The 1,3-diphenylisobenzofuran oxidation reaction was investigated in methanolic and dodecylammonium propionate reversed micellar solutions using fluorescein sodium as photosensitizer. It was found that aniline remarkably enhanced the furan oxidation in methanolic solutions but inhibited it in reversed micellar solut...
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Singlet Oxygen, Pyrene, Diphenylisobenzofuran, Micelles The reaction of singlet oxygen with 1,3-diphenylisobenzofuran was investigated in aqueous micellar solutions of sodium dodecyl sulfate and dodecyl trimethylammonium chloride using pyrene as photosensitizer. Singlet oxygen, produced by the photosensitization of pyrene bound to micelles, oxidized efficiently 1,3-diphenylisobenzofuran bound t...
متن کاملOn the reaction of 1,3-diphenylisobenzofuran and (2-iodoethynyl)(phenyl)iodonium triflate. A unique case of oxygen transfer from the Diels-Alder adduct to the diene.
Reaction of 1,3-diphenylisobenzofuran (DPIBF) with 2-(iodoethynyl)(phenyl)-iodonium triflate at room temperature gave the expected Diels-Alder adduct, but using an excess of DFIBF (2 equiv.) and performing the reaction at 55 °C or heating at this temperature during the concentration stage, the initial orange solution or product mixture became dark brown and the products 1,2-phenylene-1,2-bis(ph...
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The aim of the present study is to compare different analytical methods for singlet oxygen and to discuss an appropriate way to evaluate the yield of singlet oxygen photogenerated from photosensitizers. Singlet oxygen photogenerated from rose bengal was evaluated by electron spin resonance analysis using sterically hindered amines, spectrophotometric analysis of 1,3-diphenylisobenzofuran oxidat...
متن کاملSinglet Oxygen Production Photosensitized by Fluorescein in Reversed Micellar Solutions
The quantum yield of singlet oxygen production was investigated in dodecylammonium propionate reversed micellar solutions containing 1,3-diphenylisobenzofuran and fluorescein as photosensitizer. The quantum yield was highly enhanced by the binding of fluorescein to reversed micelles, and increased with decreasing the solubilized water content in reversed micelles. Results obtained was discussed...
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